Author(s):
Shivani Bharti, Kedar Singh

Abstract:
Transition metal dichalcogenide (TMDs) quantum dots (QDs) have attracted widespread attention among scientific community as fluorescent nanomaterial. Among TMDs, MoS2 has received particular interest due to its novel and intriguing optical properties. In this work hydrothermal method is used to prepare aqueous soluble MoS2 QDs using Molybdenyl acetylacetonate and thiourea as Mo and S precursors, respectively. The solubility of unfunctionalized MoS2 is poor in water and organic solvent, therefore thioglycolic acid is used as surfactant for surface functionalization and to enhance the aqueous solubility & stability. These functionalized QDs have been synthesized at pH 11 using hydrothermal method and explored their structural and optical properties. The as synthesized QDs are characterized using TEM, XRD, FTIR, UV-Vis and PL spectroscopy. The morphological shape of as prepared QDs is spherical with size 4-6.5 nm. The MAA encapsulated MoS2 QDs are further explored as fluorescent probe for the sensitive sensing of flavonoid Quercetin.

Pages: 197-203

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